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Tris(pentafluorophenyl)borane 三(五氟苯基)硼

規格: 98%

CAS: 1109-15-5

產品編號: H54283

MDL: MFCD00269813

品牌: INFI

Chemical Name	Tris(Pentafluorophenyl)Borane
MDL Number	MFCD00269813
PubChem Substance ID	87558752
CAS Number	1109-15-5
Reaxys-RN	2931347
Merck Number	9755
Synonym	Tris(perfluorophenyl)borane {LY} Tris(perfluorophenyl)borane {} {LY} Tris(perfluorophenyl)borane {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(pe
Beilstein Registry Number	2931347
EC Number	250-023-7
Chemical Name Translation	三(五氟苯基)硼烷
LabNetwork Molecule ID	LN00145630
InChI	InChI=1S/C18BF15/c20-4-1(5(21)11(27)16(32)10(4)26)19(2-6(22)12(28)17(33)13(29)7(2)23)3-8(24)14(30)18(34)15(31)9(3)25
Canonical SMILES	FC1=C(B(C2=C(F)C(F)=C(F)C(F)=C2F)C3=C(F)C(F)=C(F)C(F)=C3F)C(F)=C(F)C(F)=C1F

GHS Symbol

WGK Germany	3
Precautionary statements
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉塵/煙/氣體/煙霧/蒸汽/噴霧。 P264 Wash hands thoroughly after handling. 處理后要徹底洗凈雙手。 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防護手套/防護服/眼睛的保護物/面部保護物。 P302+P352+P332+P313+P362+P364 P305+P351+P338 P305+P351+P338+P337+P313 P362 Take off contaminated clothing and wash before reuse. 脫掉污染的衣服，清洗后方可重新使用
Hazard statements
H315 Causes skin irritation 會刺激皮膚 H319 Causes serious eye irritation 嚴重刺激眼睛 H335 May cause respiratory irritation 可能導致呼吸道刺激
Hazard Codes	T Xi Xi,T,N,Xn,F
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Gloves
Signal word	Warning
Storage condition	2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen <0°C <;0 Moisture Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {}
Safety Statements
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接觸后，立即用大量水沖洗并征求醫生意見； S36 Wear suitable protective clothing 穿戴適當的防護服； S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴適當的防護服、手套和眼睛/面保護； S37/39 Wear suitable gloves and eye/face protection 穿戴適當的手套和眼睛/面保護； S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 發生事故時或感覺不適時，立即求醫（可能時出示標簽）； S60 This material and its container must be disposed of as hazardous waste 該物質及其容器必須作為危險廢物處置； S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免釋放到環境中，參考特別指示/安全收據說明書； S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求醫并出示該容器或標簽；
UN Number	UN 1268 3/PG 2 UN2811
Risk Statements
R36/37/38 Irritating to eyes, respiratory system and skin 對眼睛、呼吸系統和皮膚有刺激性
Packing Group	III
Hazard Class	6.1

A useful component of Ziegler-Nattametallocene catalyst for polyolefins.

{ALFA} Air-stable, water-tolerant Lewis acid; for a review, see: Chem. Soc. Rev., 26, 345 (1997). Introduced by Yamamoto as a catalyst (2 mol%) for aldol condensations between silyl enol ethers and aldehydes under extremely mild conditions at temperatures between -78o and ambient. Also effective for Michael additions of silyl enol ethers with enones: Synlett, 577 (1993). Low-temperature condensation of ester enol silanes with imines provides a route to ß-amino esters: Synlett, 963 (1994). Superior catalyst to TBAF for O-silylation with trialkyl or triaryl silanes. Alcohols and phenols are silylated using 2-8 mol% catalyst, with secondary and tertiary alcohols reacting faster than primary: J. Org. Chem., 64, 4887 (1999). Effective catalyst for reduction with Triethylsilane, A10320, of alcohols and ethers to alkyls: Tetrahedron Lett., 40, 8919 (1999). Catalyst for highly efficient hydrosilylation of olefins with silanes R3SiH: J. Org. Chem., 67, 1936 (2002).

{ALF} Air-stable, water-tolerant Lewis acid; for a review, see: Chem. Soc. Rev., 26, 345 (1997). Introduced by Yamamoto as a catalyst (2 mol%) for aldol condensations between silyl enol ethers and aldehydes under extremely mild conditions at temperatures between

{ALFA} Catalyst for regioselective rearrangement of epoxides to carbonyl compounds: Synlett., 721 (1995), and efficient cleavage of epoxides with allyl and propargyl alcohols, amines and thiols: Tetrahedron Lett., 43, 3801 (2002).

{SA} J. Am. Chem. Soc. 129 , 1880, (2007) 摘要

{SA} Merck 14 ,9755

1109-15-5 H54283 Tris(pentafluorophenyl)borane
三(五氟苯基)硼

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化學屬性

Mol. Formula	C18BF15
Mol. Weight	512
Melting Point	126 - 131°C（lit。）
TSCA	Yes
Density	0.71
Refractive index	n20/D 1.41
Flash Point	7 °C
Stability	對熱敏感，對濕度敏感
Appearance	off-white pwdr.
Boiling Point	327.3±42.0 °C at 760 mmHg

*以上化合物性質及應用等信息僅供參考