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Bis(cyclopentadienyl)zirconium dichloride 二氯二茂鋯

規格: 98%

CAS: 1291-32-3

產品編號: H76122

MDL: MFCD00003726

品牌: INFI

Chemical Name	Bis(cyclopentadienyl)zirconium dichloride
Synonym	Bis(cyclopentadienyl)zirconium(IV) dichloride {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {} {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {} {} {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {} {} {} {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {} {} {} {} {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {} {} {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)zirconium(IV
CAS Number	1291-32-3
EC Number	215-066-8
Beilstein Registry Number	2384789
MDL Number	MFCD00003726
PubChem Substance ID	87577925
Chemical Name Translation	二氯二茂鋯
Wiswesser Line Notation	L50J 0-ZR-GG- 0L50J
LabNetwork Molecule ID	LN01746727
Canonical SMILES	[][Zr](Cl)(Cl)[].c1cccc1.c2cccc2

GHS Symbol

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 30 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NCIUS* Progress Report for Contract No. PH-43-64-886, Submitted to the
   National Cancer Institute by The Institute of Chemical Biology, University
   of San Francisco.  (San Francisco, CA 94117)  Volume(issue)/page/year:
   PH43-64-886

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 333 ug/plate
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   11(Suppl 12),1,1988

Signal word	Danger
WGK Germany	3
Safety Statements
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接觸后，立即用大量水沖洗并征求醫生意見； S36 Wear suitable protective clothing 穿戴適當的防護服； S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴適當的防護服、手套和眼睛/面保護； S37 Wear suitable gloves 戴適當手套； S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 發生事故時或感覺不適時，立即求醫（可能時出示標簽）； S60 This material and its container must be disposed of as hazardous waste 該物質及其容器必須作為危險廢物處置； S9 Keep container in a well-ventilated place 保持容器在通風良好的場所；
Risk Statements
R34 Causes burns 會導致灼傷 R36/37/38 Irritating to eyes, respiratory system and skin 對眼睛、呼吸系統和皮膚有刺激性
Precautionary statements
P234 Keep only in original container. 只保留在原來的容器中。 P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉塵/煙/氣體/煙霧/蒸汽/噴霧。 P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉塵/煙/氣體/煙霧/蒸汽/噴霧。 P264 Wash hands thoroughly after handling. 處理后要徹底洗凈雙手。 P270 Do not eat, drink or smoke when using this product. 使用本產品時不要吃東西，喝水或吸煙。 P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通風良好的地方使用。 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防護手套/防護服/眼睛的保護物/面部保護物。 P301+P330+P331 P303+P361+P353 P303+P361+P353+P310+P363 P305+P351+P338 P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或醫生/醫師。 P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大損害。 P405 Store locked up. 上鎖保管。 P501 Dispose of contents/container to..… 處理內容物/容器.....
RTECS	ZH7525000
Hazard statements
H315 Causes skin irritation 會刺激皮膚 H319 Causes serious eye irritation 嚴重刺激眼睛 H335 May cause respiratory irritation 可能導致呼吸道刺激 H290 May be corrosive to metals 可能腐蝕金屬。
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Gloves
Packing Group	III
UN Number	3261
Storage condition	2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Air & Moisture Sensitive Refrigerator (+4°C) {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored un
Hazard Codes	8 Xi
Hazard Class	8

用于合成許多早期過渡金屬絡合物和有機金屬化合物

{uni_hamburg} Short: III/35D5

{ALF}

{uni_hamburg} Short: III/20b

{ALF} For reaction of alkene-zirconocene complexes with cyclic enol ethers, see: Angew. Chem. Int. Ed., 43, 3932 (2004).

{ALF} Versatile organometallic reagent and catalyst. For a brief review, see: Synlett, 375 (1999). Other reviews: Organozirconium compounds in organic synthesis: Synthesis, 1 (1988); Recent advances in the chemistry of zirconocene and related compounds: Tetrahedron, 51, 4255 (1995); Synthetic applications of zirconocene complexes: Tetrahedron, 52, 12853 (1996). Formation of carbon-carbon bonds via 'zirconocene' (obtained by reaction of the dichloride with Grignard or lithium reagents): Synlett, 299 (1995). Reduction with n-BuLi in the presence of 2-butyne leads to a zirconium metallocycle: Tetrahedron Lett., 27, 2829 (1986), which is a useful intermediate for the synthesis of phospholes and analogous heterocycles in which the Zr atom is replaced by As, Sb, Bi, Si, Ge, Sn, Ga, S, Se or B: Org. Synth. Coll., 9, 653 (1998), and references therein:

1291-32-3 H76122 Bis(cyclopentadienyl)zirconium dichloride
二氯二茂鋯

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化學屬性

Mol. Formula	C10H10Cl2Zr
Mol. Weight	292.32
Density	1.422
Melting Point	242-245°C
TSCA	Yes
Boiling Point	124-125 °C at 15 mmHg
Solubility	水解
Stability	對濕度敏感
Flash Point	124-125°C/15mm
Appearance	white to off-white pwdr.
Redox	Reduction

*以上化合物性質及應用等信息僅供參考